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[1] Miao Jiangping** Xu Jin Zhou Lixin Wu Zonghan Raymand Hii Chai Koh Hoong Lin Yihua,. Study of the Conductance Characteristicof Doped Polymer by Monte Carlo Method* [J]. Journal of Southeast University (English Edition), 2002, 18 (2): 188-190. [doi:10.3969/j.issn.1003-7985.2002.02.018]
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Study of the Conductance Characteristicof Doped Polymer by Monte Carlo Method*()
掺杂法提高聚合物电导率的蒙特卡洛法讨论
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Journal of Southeast University (English Edition)[ISSN:1003-7985/CN:32-1325/N]

Volumn:
18
Issue:
2002 2
Page:
188-190
Research Field:
Mathematics, Physics, Mechanics
Publishing date:
2002-06-30

Info

Title:
Study of the Conductance Characteristicof Doped Polymer by Monte Carlo Method*
掺杂法提高聚合物电导率的蒙特卡洛法讨论
Author(s):
Miao Jiangping1** Xu Jin1 Zhou Lixin1 Wu Zonghan1 Raymand Hii2 Chai Koh Hoong2 Lin Yihua3
1Department of Physics, Southeast University, Nanjing 210096, China
2Kede Chemical Industry Co. Ltd., Guangzhou 510600, China
3Anhui Science Technology Press, Hefei 230063, China
缪江平1, 徐进1, 周立新1, 吴宗汉1, Raymand Hii2, Chai Koh Hoong2, 林义华3
1东南大学物理系, 南京 210096; 2广州科德化工有限公司, 广州 510600; 3安徽科学技术出版社, 合肥 230063
Keywords:
conductance;  doping;  polymer;  Monte Carlo method
电导;  掺杂;  聚合物;  蒙特卡洛法
PACS:
O488
DOI:
10.3969/j.issn.1003-7985.2002.02.018
Abstract:
The conduct mechanism of the doped polymer is considered. In an asymmetry system composed of high polymer and doping conductive matte, chain or congeries framework will be formed between the conductive particles to improve the conductance characteristic. In this procession, the conductive particles interact to each other. In this paper, we describe the conductance of the doped polymer by Monte Carlo method. The results accord with the experiments quite well. It can be concluded that there is an evident change of doped polymer from nonconductor to metal.
掺杂法提高聚合物电导的机理是考虑导电填充物和高聚物所构成的不均匀体系中, 导电颗粒间会形成链式组织或聚集体组织而提高导电性能, 在此过程中导电颗粒有相互作用.本文是采用蒙特卡洛法对掺杂高分子材料的电导特性作了研究, 研究结果与实验符合较好, 并得出存在剧变特征的所谓绝缘体——金属相变特性的计算结果.

References:

[1] Wu Z H, Zhou G. The study of conductance mechanism of the conductive low-dimension SPcCuOH L-B film[J]. Sensor Technology Transaction, 1989(4): 9-12.
[2] Uhlherr A. Multiple chain Monte Carlo method for atomistic simulation of high molecular weight polymer melts[J]. Computational and Theoretical Polymer Science, 2000(10):29-41.
[3] Chung I. Monte Carlo simulation of free radical telomerization[J]. Polymer, 2000(15):5643-5651
[4] Zhao Z Q. The resist-static technology of macromolecule materials[M]. Beijing: Textile Industry Press, 1991.227-236.(in Chinese)

Memo

Memo:
* The project supported by the National Natural Science Foundation of China(59977002).
** Born in 1972, male, graduate.
Last Update: 2002-06-20