[1] Qiu Fengxian, Zhou Yuming, Yang Yanfang, Liu Juzheng, et al. Synthesis and electro-optic propertiesof fluorine-containing polyimide [J]. Journal of Southeast University (English Edition), 2007, 23 (1): 131-134. [doi:10.3969/j.issn.1003-7985.2007.01.026]
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Synthesis and electro-optic propertiesof fluorine-containing polyimide(
)
)Journal of Southeast University (English Edition)[ISSN:1003-7985/CN:32-1325/N]
- Volumn:
- 23
- Issue:
- 2007 1
- Page:
- 131-134
- Research Field:
- Chemistry and Chemical Engineering
- Publishing date:
- 2007-03-30
Info
- Title:
- Synthesis and electro-optic propertiesof fluorine-containing polyimide
- Author(s):
- Qiu Fengxian1; Zhou Yuming2; Yang Yanfang3; Liu Juzheng2; Cao Zhuangqi3
-
1School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, China
2 School of Chemistry and Chemical Engineering, Southeast University, Nanjing 210096, China
3Guided Wave Optoelectronics Device Laboratory, Department of Physics, Shanghai Jiaotong University, Shanghai 200240, China
- Keywords:
- nonlinear optical; electro-optic property; polyimide
- PACS:
- O631;TH744
- DOI:
- 10.3969/j.issn.1003-7985.2007.01.026
- Abstract:
- The fluorine-containing organic polymer was synthesized from 3, 3’, 4, 4’-Bisphenyltetracarboxylic(BPDA), and 2, 2-Bis(3-amino-4-hydroxyyphenyl)hexafluoropropane(6FHP).It is a first-step preparation of a preimided hydroxy-containing polyimide, followed by the covalent bonding of an active chromophore, dispersed red 19(DR19), onto the backbone of the polyimide via the Mitsunobu reaction.The nonlinear optical(NLO)containing polyimide was synthesized.The differential scanning calorimeter(DSC)and thermal gravimetric analysis(TGA)exhibited Tg and the temperature Td at which 5% mass losses occurring of polymer were 248 and 309 ℃, respectively.A reflective electro-optic(EO)modulator using this polymer was fabricated.The optical nonlinearities were determined to be d33=5.209×10-9esu(poling voltage of 3.6 kV, 205 ℃)and d33=7.418×10-9esu(poling voltage of 3.8 kV, 210 ℃)by the second harmonic generation method in in-situ condition at a fundamental wavelength of 1 064 nm.The EO coefficients γ33 of the polymer layer in the EO modulator were determined to be 2.182 pm/V(poling voltage of 3.6 kV, 205 ℃)and 3.107 pm/V(poling voltage of 3.8 kV, 210 ℃)at 1 064 nm by an attenuated-total-reflection(ATR)method.
References:
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Memo
- Memo:
- Biography: Qiu Fengxian(1965—), female, associate professor, fxqiuchem@163.com.