|Table of Contents|

[1] Sun Rongyue, Li Yingjie,. Synthesis of highly reactive sorbent from industrial wastesand its CO2 capture capacity [J]. Journal of Southeast University (English Edition), 2015, 31 (2): 209-214. [doi:10.3969/j.issn.1003-7985.2015.02.009]
Copy

Synthesis of highly reactive sorbent from industrial wastesand its CO2 capture capacity()
Share:

Journal of Southeast University (English Edition)[ISSN:1003-7985/CN:32-1325/N]

Volumn:
31
Issue:
2015 2
Page:
209-214
Research Field:
Chemistry and Chemical Engineering
Publishing date:
2015-06-20

Info

Title:
Synthesis of highly reactive sorbent from industrial wastesand its CO2 capture capacity
Author(s):
Sun Rongyue1 2 Li Yingjie1
1School of Energy and Power Engineering, Shandong University, Jinan 250061, China
2School of Energy and Power Engineering, Nanjing Institute of Technology, Nanjing 211167, China
Keywords:
carbide slag synthetic CO2 sorbent CO2 capture
PACS:
TQ534
DOI:
10.3969/j.issn.1003-7985.2015.02.009
Abstract:
A kind of industrial solid waste, i.e., carbide slag, was used as CaO precursor to synthesize CO2 sorbent. The highly reactive synthetic sorbent was prepared from carbide slag, aluminum nitrate hydrate and glycerol water solution by the combustion synthesis method. The results show that the synthetic sorbent exhibits a much higher CO2 capture capacity compared with carbide slag. The CO2 capture capacity and the carbonation conversion of the synthetic sorbent are 0.38 g/g and 0.70 after 50 cycles, which are 1.8 and 2.1 times those of carbide slag. The average carbonation conversion and the CO2 capture efficiency of the synthetic sorbent are higher than those of carbide slag with the same sorbent flow ratios. The required sorbent flow ratios are lower for synthetic sorbent to achieve the same CO2 capture efficiency compared with carbide slag. With the same sorbent flow ratio and CO2 capture efficiency, the energy requirement in calciner for the synthetic sorbent is less than that for carbide slag.

References:

[1] Li Y J, Sun R Y, Liu C T, et al. CO2 capture by carbide slag from chlor-alkali plant in calcination/carbonation cycles [J]. Int J Greenhouse Gas Control, 2012, 9:117-123.
[2] Miró L, Navarro M E, Suresh P, et al. Experimental characterization of a solid industrial by-product as material for high temperature sensible thermal energy storage(TES)[J]. Appl Energy, 2014, 113:1261-1268.
[3] Sharma V K, Fortuna F, Mincarini M, et al. Disposal of waste tyres for energy recovery and safe environment [J]. Appl Energy, 2000, 65(1/2/3/4):381-394.
[4] Sanna A, Dri M, Hall M R, et al. Waste materials for carbon capture and storage by mineralisation(CCSM)—a UK perspective [J]. Appl Energy, 2012, 99:545-554.
[5] Bobicki E R, Liu Q, Xu Z, et al. Carbon capture and storage using alkaline industrial wastes [J]. Prog Energy Combust Sci, 2012, 38(2):302-320.
[6] Valverde J M, Sanchez-Jimenez P E, Perez-Maqueda L A, et al. Role of crystal structure on capture by limestone derived CaO subjected to carbonation/recarbonation/calcination cycles at Ca-looping conditions [J]. Appl Energy, 2014, 125:264-275.
[7] Lin S Y, Harada M, Suzuki Y, et al. Process analysis for hydrogen production by reaction integrated novel gasification(HyPr-RING)[J]. Energy Convers Manage, 2005, 46(6):869-880.
[8] Liu W, An H, Qin C, et al. Performance enhancement of calcium oxide sorbents for cyclic CO2 capture—a review [J]. Energy Fuels, 2012, 26(5):2751-2567.
[9] Ridha F N, Manovic V, Macchi A, et al. The effect of SO2 on CO2 capture by CaO-based pellets prepared with a kaolin derived Al(OH)3 binder [J]. Appl Energy, 2012, 92:415-420.
[10] Zhang M, Peng Y, Sun Y, et al. Preparation of CaO-Al2O3 sorbent and CO2 capture performance at high temperature [J]. Fuel, 2013, 111:636-642.
[11] Zhou Z, Qi Y, Xie M, et al. Synthesis of CaO-based sorbents through incorporation of alumina/aluminate and their CO2 capture performance [J]. Chem Eng Sci, 2012, 74:172-180.
[12] Chen H, Zhao C, Yu W. Calcium-based sorbent doped with attapulgite for CO2 capture [J]. Appl Energy, 2013, 112:67-74.
[13] Chen H C, Zhao C S, Yang Y M, et al. CO2 capture and attrition performance of CaO pellets with aluminate cement under pressurized carbonation [J]. Appl Energy, 2012, 91:334-340.
[14] García E, Laca M, Pérez E, et al. New class of acetal derived from glycerin as a biodiesel fuel component [J]. Energy Fuels, 2008, 22(6): 4274-4280.
[15] Liu C T. Cyclic carbonation characteristics of modified carbide slag as a CO2 sorbent in high temperature [D]. Jinan: School of Energy and Power Engineering, Shandong University, 2014.(in Chinese)
[16] Li Y J, Zhao C S, Chen H C, et al. CO2 capture efficiency and energy requirement analysis of power plant using modified calcium-based sorbent looping cycle [J]. Energy, 2011, 36(3):1590-1598.
[17] Abanades J C. The maximum capture efficiency of CO2 using a carbonation/calcination cycle of CaO/CaCO3 [J]. Chem Eng J, 2002, 90(3):303-306.

Memo

Memo:
Biographies: Sun Rongyue(1986—), male, graduate; Li Yingjie(corresponding author), male, doctor, associate professor, liyj@sdu.edu.cn.
Foundation item: The National Natural Science Foundation of China(No.51376003).
Citation: Sun Rongyue, Li Yingjie.Synthesis of highly reactive sorbent from industrial wastes and its CO2 capture capacity[J].Journal of Southeast University(English Edition), 2015, 31(2):209-214.[doi:10.3969/j.issn.1003-7985.2015.02.009]
Last Update: 2015-06-20