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[1] Wang Ligang, Chen Changhe, Kruse H.Kolker,. Modeling mercury adsorption on carbon particlesin simulated flue gas [J]. Journal of Southeast University (English Edition), 2006, 22 (2): 256-259. [doi:10.3969/j.issn.1003-7985.2006.02.023]
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Modeling mercury adsorption on carbon particlesin simulated flue gas()
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Journal of Southeast University (English Edition)[ISSN:1003-7985/CN:32-1325/N]

Volumn:
22
Issue:
2006 2
Page:
256-259
Research Field:
Environmental Science and Engineering
Publishing date:
2006-06-30

Info

Title:
Modeling mercury adsorption on carbon particlesin simulated flue gas
Author(s):
Wang Ligang1 Chen Changhe2 Kruse H.Kolker3
1Department of Thermal Engineering, University of Science and Technology, Beijing 100083, China
2Department of Thermal Engineering, Tsinghua University, Beijing 100084, China
3Department of Chemical Engineering, University of North Dakota, Grand Forks, ND 58202, USA
Keywords:
mercury adsorption residual carbon fly ash activated carbon
PACS:
X701
DOI:
10.3969/j.issn.1003-7985.2006.02.023
Abstract:
A model was developed to describe the adsorption characteristic of mercury in flue gas based on one residual carbon sample and one activated carbon sample.The differential equations were established with mass balance of mercury in the gas phase and in the solid phase.Then the model was solved using a Matlab program with a Runge-Kutta process.The mercury adsorption isotherms of these two adsorbents were obtained by breakthrough column experiments.The results show that at low gas phase mercury concentrations(<0.3 mg/m3), the adsorption equilibrium of residual carbon is in accord with the case of a type Ⅱ isotherm of the Freundich theory.Whereas the data of activated carbon falls into the Langmuir relationship, it is the case of a type Ⅲ isotherm.The experimental data were fitted to the Freundlich model by Matlab software.The variances of mercury concentration are smaller than 0.81 which implies the agreement between measurements and simulation is quite agreeable considering the wide scatter of the measurements.This model is useful for forecasting mercury removal efficiency and is helpful to the mechanism analysis of mercury adsorption on carbon-based adsorbent.

References:

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Memo

Memo:
Biography: Wang Ligang(1970—), male, doctor, lecturer, wangligang@me.ustb.edu.cn.
Last Update: 2006-06-20